
Cyclic oligoadenylates such as c-tetraAMP (Biolog Cat. No. C 335) were found to be novel bacterial second messengers involved in the Type III CRISPR-Cas-associated detection and degradation of invasive genetic elements in many prokaryotes. 2′,2”,2”’,2””-Tetra-c-tetradAMP is an analogue of c-tetraAMP containing deoxy modifications in all ribose 2′-positions, which are expected to make the compound resistant to degradation by nucleases.
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